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Author (up) Nogueira, G.; Stigter, T.Y.; Zhou, Y.; Mussa, F.; Juizo, D.
Title Understanding groundwater salinization mechanisms to secure freshwater resources in the water-scarce city of Maputo, Mozambique Type Journal Article
Year 2019 Publication Science of The Total Environment Abbreviated Journal
Volume 661 Issue Pages 723-736
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Abstract In this study hydrochemical, isotopic and multivariate statistical tools are combined with a recharge analysis and existing geophysical data to improve understanding of major factors controlling freshwater occurrence and the origins of high salinities in the multi-layered coastal aquifer system of the Great Maputo area in Mozambique. Access to freshwater in this semi-arid area is limited by an inefficient public supply network, scarce surface waters, long droughts and an increasing population growth. Groundwater has a large potential to enhance water security, but its exploitation is threatened by both coastal and inland salinization mechanisms that are poorly understood. A GIS approach is utilized to classify potential recharge zones based on hydrogeological properties and land use/cover, whereas potential recharge rates are estimated through a root zone water balance method. In combination with water stable isotope data results reveal that extreme rainfall events provide the most relevant contributions to recharge, and interception and evaporation play an important role in the low recharge areas. Hierarchical clustering of hydrochemical and isotopic data allows the classification of six water groups, varying from fresh to brackish/salt waters. Corresponding scatter plots and PHREEQC modelling show evaporation and mixing with seawater (up to 5%) as major processes affecting salinity in the area. The co-occurrence of high alkalinity and Cl concentrations, in combination with piezometric and geo-electrical data, suggests that: 1) inland brackish/salt groundwater is caused by mixing with seawater trapped within clay layers; and 2) brackish/salt surface waters result from seepage of brackish groundwater into rivers and wetlands, followed by evaporation, hence increasing salinity and δ18O values. Mixing with small fractions of trapped seawater as main salinity source, rather than halite dissolution, is further corroborated by Br/Cl ratios of brackish/salt water samples near the ocean ratio. Cation exchange upon salinization is mainly observed in the semi-confined aquifer, while freshening takes place in the phreatic aquifer, particularly in areas presenting high recharge rates.
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ISSN 0048-9697 ISBN Medium
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Call Number THL @ christoph.kuells @ Nogueira2019 Serial 34
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Author (up) Oehler, T.; Tamborski, J.; Rahman, S.; Moosdorf, N.; Ahrens, J.; Mori, C.; Neuholz, R.Ã.©; Schnetger, B.; Beck, M.
Title DSi as a Tracer for Submarine Groundwater Discharge Type Journal Article
Year 2019 Publication Frontiers in Marine Science Abbreviated Journal
Volume 6 Issue Pages 563
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Abstract Submarine groundwater discharge (SGD) is an important source of nutrients and metals to the coastal ocean, affects coastal ecosystems, and is gaining recognition as a relevant water resource. SGD is usually quantified using geochemical tracers such as radon or radium. However, a few studies have also used dissolved silicon (DSi) as a tracer for SGD, as DSi is usually enriched in groundwater when compared to surface waters. In this study, we discuss the potential of DSi as a tracer in SGD studies based on a literature review and two case studies from contrasting environments. In the first case study, DSi is used to calculate SGD fluxes in a tropical volcanic-carbonate karstic region (southern Java, Indonesia), where SGD is dominated by terrestrial groundwater discharge. The second case study discusses DSi as a tracer for marine SGD (i.e., recirculated seawater) in the tidal flat area of Spiekeroog (southern North Sea), where SGD is dominantly driven by tidal pumping through beach sands. Our results indicate that DSi is a useful tracer for SGD in various lithologies (e.g., karstic, volcanic, complex) to quantify terrestrial and marine SGD fluxes. DSi can also be used to trace groundwater transport processes in the sediment and the coastal aquifer. Care has to be taken that all sources and sinks of DSi are known and can be quantified or neglected. One major limitation is that DSi is used by siliceous phytoplankton and therefore limits its applicability to times of the year when primary production of siliceous phytoplankton is low. In general, DSi is a powerful tracer for SGD in many environments. We recommend that DSi should be used to complement other conventionally used tracers, such as radon or radium, to help account for their own shortcomings.
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ISSN 2296-7745 ISBN Medium
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Call Number THL @ christoph.kuells @ Oehler2019 Serial 192
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Author (up) Qi, H.; Ma, C.; He, Z.; Hu, X.; Gao, L.
Title Lithium and its isotopes as tracers of groundwater salinization: A study in the southern coastal plain of Laizhou Bay, China Type Journal Article
Year 2019 Publication The Science of the Total Environment Abbreviated Journal Sci Total Environ
Volume 650 Issue Pt 1 Pages 878-890
Keywords Brine and seawater intrusion; Groundwater salinization; Hydrochemistry; Lithium isotope; Southern coastal plain of Laizhou Bay
Abstract In the southern coastal plain of Laizhou Bay, due to intensive exploitation of groundwater since the early 1970s, the shallow aquifer has been severely influenced by saltwater intrusion, which causes the extraction to shift from shallow to deeper aquifer changing the hydrogeological condition greatly. This study was conducted to investigate the groundwater salinization using hydrochemistry and H, O and Li isotope data. Dissolved Li shows a linear correlation with Cl and Br in seawater, brine and saline groundwater indicating the marine Li source, whereas the enrichment of Li in surface water, brackish and fresh groundwater is impacted by dissolution of silicate minerals. The analyses of hydrochemistry and isotopes (H, O and Li) indicate that brine originated from seawater evaporation, followed by mixing processes and some water-rock interactions; shallow saline groundwater originated from brine diluted with seawater and fresh groundwater; deep saline groundwater originated from seawater intrusion. The negative correlation of δ(7)Li and Li/Na in surface water, brackish and fresh groundwater is contrary to the general conclusion, indicating the slow weathering of silicate minerals and hydraulic interaction between surface water and shallow groundwater in this area. The analyses of hydrochemistry and isotopes (Li, H and O) can well identify the salinity sources and isotope fractionation in groundwater flow and mixing, especially groundwater with high TDS. As both mixing with saltwater and isotope fractionation can explain the combination of high δ(7)Li and low TDS in brackish groundwater, isotope fractionation may limit their use in recognizing salinity sources of groundwater with low TDS.
Address School of Environmental Studies, China University of Geosciences, Wuhan 430074, China
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Notes PMID:30308862 Approved no
Call Number THL @ christoph.kuells @ Serial 184
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Author (up) Ranjbar*, A.; Ehteshami, M.
Title Spatio‑temporal mapping of salinity in the heterogeneous coastal aquifer Type Journal Article
Year 2019 Publication Appl. Water Sci. Abbreviated Journal
Volume 9 Issue Pages 32
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Call Number CUT @ phaedon.kyriakidis @ Ranjbar2019 Serial 137
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Author (up) Stoeckl, L.; Walther, M.; Morgan, L.K.
Title Physical and Numerical Modelling of Post-Pumping Seawater Intrusion Type Journal Article
Year 2019 Publication Geofluids Abbreviated Journal
Volume 2019 Issue Pages 11
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Call Number THL @ christoph.kuells @ Stoeckl.2019 Serial 16
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