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Author |
Qi, H.; Ma, C.; He, Z.; Hu, X.; Gao, L. |
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Title |
Lithium and its isotopes as tracers of groundwater salinization: A study in the southern coastal plain of Laizhou Bay, China |
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Journal Article |
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Year |
2019 |
Publication |
The Science of the Total Environment |
Abbreviated Journal  |
Sci Total Environ |
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Volume |
650 |
Issue |
Pt 1 |
Pages |
878-890 |
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Keywords |
Brine and seawater intrusion; Groundwater salinization; Hydrochemistry; Lithium isotope; Southern coastal plain of Laizhou Bay |
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Abstract |
In the southern coastal plain of Laizhou Bay, due to intensive exploitation of groundwater since the early 1970s, the shallow aquifer has been severely influenced by saltwater intrusion, which causes the extraction to shift from shallow to deeper aquifer changing the hydrogeological condition greatly. This study was conducted to investigate the groundwater salinization using hydrochemistry and H, O and Li isotope data. Dissolved Li shows a linear correlation with Cl and Br in seawater, brine and saline groundwater indicating the marine Li source, whereas the enrichment of Li in surface water, brackish and fresh groundwater is impacted by dissolution of silicate minerals. The analyses of hydrochemistry and isotopes (H, O and Li) indicate that brine originated from seawater evaporation, followed by mixing processes and some water-rock interactions; shallow saline groundwater originated from brine diluted with seawater and fresh groundwater; deep saline groundwater originated from seawater intrusion. The negative correlation of δ(7)Li and Li/Na in surface water, brackish and fresh groundwater is contrary to the general conclusion, indicating the slow weathering of silicate minerals and hydraulic interaction between surface water and shallow groundwater in this area. The analyses of hydrochemistry and isotopes (Li, H and O) can well identify the salinity sources and isotope fractionation in groundwater flow and mixing, especially groundwater with high TDS. As both mixing with saltwater and isotope fractionation can explain the combination of high δ(7)Li and low TDS in brackish groundwater, isotope fractionation may limit their use in recognizing salinity sources of groundwater with low TDS. |
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School of Environmental Studies, China University of Geosciences, Wuhan 430074, China |
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English |
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ISSN |
0048-9697 |
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Notes |
PMID:30308862 |
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no |
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Call Number |
THL @ christoph.kuells @ |
Serial |
184 |
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Author |
Siarkos, I.; Latinopoulos, P. |
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Title |
Modeling seawater intrusion in overexploited aquifers in the absence of sufficient data: application to the aquifer of Nea Moudania, northern Greece |
Type |
Journal Article |
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Year |
2016 |
Publication |
Hydrogeology Journal |
Abbreviated Journal |
Hydrogeology J. |
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Volume |
24 |
Issue |
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Pages |
2123–2141 |
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Keywords |
Groundwater flow, Seawater intrusion, Numerical modeling, Greece, Sensitivity analysis |
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Abstract |
In many coastal areas, overexploitation of groundwater resources has led both to the quantitative degradation of local aquifers and the deterioration of groundwater quality due to seawater intrusion. To investigate the behavior of coastal aquifers under these conditions, numerical modeling is usually implemented; however, the proper implementation of numerical models requires a large amount of data, which are often not available due to the time-consuming and costly process of obtaining them. In the present study, the investigation of the behavior of coastal aquifers under the lack of adequate data is
attempted by developing a methodological framework consisting of a series of numerical simulations: a steady-state, a false-transient and a transient simulation. The sequence and the connection between these simulations constitute the backbone of the whole procedure aimed at adjusting the various
model parameters, as well as obtaining the initial conditions for the transient simulation. The validity of the proposed methodology is tested through evaluation of the model calibration procedure and the estimation of the simulation errors (mean error, mean absolute error, root mean square error, mean relative error) using the case of Nea Moudania basin, northern Greece. Furthermore, a sensitivity analysis is performed in order to minimize the error estimates and thus to maximize the reliability of the models. The results of the whole procedure affirm the proper implementation of the developed methodology under specific conditions and assumptions due to the lack of sufficient data, while they give a clear picture of the aquifer’s quantitative and qualitative status. |
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Address |
Ilias Siarkos: isiarkos@civil.auth.gr; Pericles Latinopoulos latin@civil.auth.gr |
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Corporate Author |
School of Civil Engineering, Aristotle University of Thessaloniki, GR54124 Thessaloniki, Greece |
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Publisher |
IAH |
Place of Publication |
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Springer |
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English |
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ISSN |
1431-2174 |
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Area |
Hydrogeology; groundwater modelling, sea water intrusion |
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Approved |
yes |
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Call Number |
MGRE @ redha.menani @ |
Serial |
52 |
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Author |
Tulipano, Luigi; Fidelibus, Dolores M; Panagopoulos, Andreas (eds) |
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Title |
Groundwater management of coastal karstic aquifers |
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Book Whole |
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Year |
2005 |
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Abbreviated Journal |
EUCOST Reports |
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EU |
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Tulipano, Luigi; Fidelibus, Dolores M; Panagopoulos, Andreas |
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Language |
en |
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Series Issue |
QS-NA-21-366-EN-R |
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ISBN |
92-898-0015-1 |
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Call Number |
THL @ christoph.kuells @ |
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93 |
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Author |
Rina, K.; Datta, P.S.; Singh, C.K.; Mukherjee, S. |
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Title |
Isotopes and ion chemistry to identify salinization of coastal aquifers of Sabarmati River Basin |
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Journal Article |
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Year |
2013 |
Publication |
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Abbreviated Journal |
Current Science |
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Volume |
104 |
Issue |
3 |
Pages |
335-344 |
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Abstract |
The lower reaches of the Sabarmati River Basin in Gujarat have intense agricultural and industrial activities and this part is affected by problems of groundwater salinity. Here we attempt to assess the processes governing the causes of groundwater salinity in the coastal alluvial aquifer, employing δ18O and δD isotopes in integration with ionic ratio. The different hydrochemical facies such Na–Mg–HCO3–Cl, Na–Cl–SO4, Na–Mg–Cl–HCO3–SO4 and Na–Cl of groundwater show the occurrence of complex geochemical phenomenon in the study area. Ionic ratio (such as Mg2+/Ca2+, Na+/Cl−, SO24/Cl-, K+/Cl−) and isotopic composition (δ18O and δD) of groundwater indicate that while in coastal areas seawater intrusion is taking place, in inland areas various anthropogenic activities and overexploitation have induced salinity in groundwater. Over-pumping of groundwater has also induced lateral intermixing of highly saline water in the vicinity of coastal areas with relatively fresh/low saline groundwater along specific flow pathways. |
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Current Science Association |
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ISSN |
0011-3891 |
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no |
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Call Number |
THL @ christoph.kuells @ |
Serial |
190 |
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Author |
Hanshaw, B.B.; Back, W. |
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Title |
Major geochemical processes in the evolution of carbonate—Aquifer systems |
Type |
Journal Article |
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Year |
1979 |
Publication |
Journal of Hydrology |
Abbreviated Journal |
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Volume |
43 |
Issue |
1 |
Pages |
287-312 |
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Keywords |
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Abstract |
As a result of recent advances by carbonate petrologists and geochemists, hydrologists are provided with new insights into the origin and explanation of many aquifer characteristics and hydrologic phenomena. Some major advances include the recognition that: (1) most carbonate sediments are of biological origin; (2) they have a strong bimodal size-distribution; and (3) they originate in warm shallow seas. Although near-surface ocean water is oversaturated with respect to calcite, aragonite, dolomite and magnesite, the magnesium-hydration barrier effectively prevents either the organic or inorganic formation of dolomite and magnesite. Therefore, calcareous plants and animals produce only calcite and aragonite in hard parts of their bodies. Most carbonate aquifers that are composed of sand-size material have a high initial porosity; the sand grains that formed these aquifers originated primarily as small shells, broken shell fragments of larger invertebrates, or as chemically precipitated oolites. Carbonate rocks that originated as fine-grained muds were initially composed primarily of aragonite needles precipitated by algae and have extremely low permeability that requires fracturing and dissolution to develop into aquifers. Upon first emergence, most sand beds and reefs are good aquifers; on the other hand, the clay-sized carbonate material initially has high porosity but low permeability, a poor aquifer property. Without early fracture development in response to influences of tectonic activity these calcilutites would not begin to develop into aquifers. As a result of selective dissolution, inversion of the metastable aragonite to calcite, and recrystallization, the porosity is collected into larger void spaces, which may not change the overall porosity, but greatly increases permeability. Another major process which redistributes porosity and permeability in carbonates is dolomitization, which occurs in a variety of environments. These environments include back-reefs, where reflux dolomites may form, highly alkaline, on-shore and continental lakes, and sabkha flats; these dolomites are typically associated with evaporite minerals. However, these processes cannot account for most of the regionally extensive dolomites in the geologic record. A major environment of regional dolomitization is in the mixing zone (zone of dispersion) where profound changes in mineralogy and redistribution of porosity and permeability occur from the time of early emergence and continuing through the time when the rocks are well-developed aquifers. The reactions and processes, in response to mixing waters of differing chemical composition, include dissolution and precipitation of carbonate minerals in addition to dolomitization. An important control on permeability distribution in a mature aquifer system is the solution of dolomite with concomitant precipitation of calcite in response to gypsum dissolution (dedolomitization). Predictive models developed by mass-transfer calculations demonstrate the controlling reactions in aquifer systems through the constraints of mass balance and chemical equilibrium. An understanding of the origin, chemistry, mineralogy and environments of deposition and accumulation of carbonate minerals together with a comprehension of diagenetic processes that convert the sediments to rocks and geochemical, tectonic and hydrologic phenomena that create voids are important to hydrologists. With this knowledge, hydrologists are better able to predict porosity and permeability distribution in order to manage efficiently a carbonate—aquifer system. |
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0022-1694 |
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Call Number |
THL @ christoph.kuells @ Hanshaw1979 |
Serial |
26 |
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